What holds atoms together, and how do ionic, covalent and metallic bonds differ?
Types of chemical bonds: distinguish ionic, covalent and metallic bonding in terms of electron transfer or sharing, and relate bond type to the elements involved.
A focused Regents Chemistry answer on ionic, covalent and metallic bonding: how electrons are transferred or shared, why bonds form to reach stability, the role of energy, and how to predict bond type from the elements involved.
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What this topic is asking
The Core Curriculum asks you to distinguish the three types of chemical bond: ionic, covalent and metallic. You must describe each in terms of what the valence electrons do (transfer or share), explain that atoms bond to reach a more stable arrangement, and predict the bond type from the elements involved. This underpins the rest of the bonding module and the properties of substances.
Why atoms bond
This drive toward a full outer level explains the charges ions take and the number of bonds an atom forms. Sodium has one valence electron to lose; chlorine needs one to fill its outer level; together they reach stability by transferring that electron.
Ionic bonding
Sodium chloride is the standard example: sodium () loses one electron to become , and chlorine () gains it to become . The resulting ions arrange into a regular lattice held together by attraction in all directions. Because metals have low ionization energies and nonmetals high electronegativities, the large difference favors electron transfer. Table S electronegativity values let you confirm a large difference, which signals an ionic bond.
Covalent bonding
Covalent bonding occurs between nonmetals because both atoms attract electrons strongly, so neither fully gives them up. In the two identical atoms share a pair equally (a nonpolar covalent bond); in the more electronegative chlorine pulls the shared pair toward itself (a polar covalent bond). Covalent bonding produces discrete molecules rather than an extended lattice, which gives molecular substances their distinctive low melting points.
Metallic bonding
This model, sometimes called the electron-sea model, is the Regents explanation for the characteristic properties of metals. It applies to a pure metal or an alloy, not to compounds.
Try this
Q1. State the type of bonding in magnesium oxide, . [1 point]
- Cue. Ionic, because it forms between a metal (magnesium) and a nonmetal (oxygen) by electron transfer.
Q2. Explain why energy is released when a bond forms. [1 point]
- Cue. Bonded atoms are at a lower potential energy than separate atoms, and the difference is released as the bond forms.
Exam-style practice questions
Practice questions written in the style of NYSED exam questions on this dot point, with worked answer explainers. The year tag is the paper they imitate, not the source.
Regents (Part A style)1 marksWhich type of bonding is found in a sample of copper metal? (1) ionic (2) nonpolar covalent (3) polar covalent (4) metallicShow worked answer →
A 1-point Part A item on bond type. The answer is (4) metallic.
Copper is a metal, and metals are held together by metallic bonding: positive metal ions in a "sea" of mobile, shared valence electrons. This mobile-electron model explains why metals conduct electricity and are malleable. Ionic bonding occurs between a metal and a nonmetal, and covalent bonding between nonmetals, neither of which describes a pure metal.
Markers reward identifying metallic bonding for a pure metal.
Regents (Part B-2 style)3 marksFor each substance, identify the type of bonding present. (a) (b) (c) . Justify your choice for part (a).Show worked answer →
A 3-point constructed-response item linking bond type to the elements involved.
(a) (1 point): ionic bonding, because it forms between a metal (sodium) and a nonmetal (chlorine) by electron transfer.
(b) (1 point): covalent (nonpolar covalent) bonding, because it is two identical nonmetal atoms sharing electrons equally.
(c) (1 point): metallic bonding, because magnesium is a metal with mobile valence electrons.
Justification: sodium loses its valence electron to chlorine, forming and ions that attract one another. Markers reward correct bond types and a transfer-based justification for the ionic compound.
Related dot points
- Electronegativity and bond polarity: use electronegativity differences from Table S to classify bonds as ionic, polar covalent or nonpolar covalent.
A focused Regents Chemistry answer on electronegativity difference and bond polarity: how subtracting Table S electronegativities classifies a bond as nonpolar covalent, polar covalent or ionic, and how that difference shapes the unequal sharing of electrons.
- Lewis structures and molecular polarity: draw Lewis electron-dot diagrams for simple atoms, ions and molecules, and decide whether a molecule is polar or nonpolar from its bonds and shape.
A focused Regents Chemistry answer on Lewis electron-dot diagrams and molecular polarity: how to draw dot structures for atoms, ions and small molecules, and how bond polarity together with molecular symmetry decides whether the whole molecule is polar.
- Properties of ionic, molecular and metallic substances: relate melting point, electrical conductivity, hardness and solubility to the type of bonding and structure.
A focused Regents Chemistry answer on how bonding type explains properties: why ionic solids have high melting points and conduct only when molten or dissolved, why molecular substances are soft and low-melting, and why metals conduct and are malleable.
- Intermolecular forces: describe hydrogen bonding, dipole-dipole forces and weak dispersion forces, and use them to explain trends in boiling point and the properties of water.
A focused Regents Chemistry answer on intermolecular forces: hydrogen bonding, dipole-dipole attractions and weak dispersion (van der Waals) forces, how they differ from chemical bonds, and how they explain boiling points and water's high boiling point and surface tension.
- The periodic table and its organization: explain periods, groups and the periodic law, and classify elements as metals, nonmetals or metalloids using position and physical properties.
A focused Regents Chemistry answer on how the periodic table is arranged: periods and groups, the periodic law, the families (alkali metals, alkaline earth metals, halogens, noble gases), and how to classify metals, nonmetals and metalloids from position and properties.
Sources & how we know this
- Physical Setting/Chemistry Core Curriculum — New York State Education Department (2002)
- Reference Tables for Physical Setting/Chemistry, 2011 Edition — New York State Education Department (2011)