Why does temperature stay constant while ice melts, and what does a heating curve show?
Phase changes and heating curves: name the phase changes and their energy changes, and interpret a heating or cooling curve including the plateaus.
A focused Virginia SOL Chemistry answer on phase changes under CH.4: the names and energy direction of melting, freezing, vaporization, condensation and sublimation, and how to read a heating curve, including why temperature stays constant during a phase change.
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What this topic is asking
Continuing standard CH.4, Virginia expects you to name the phase changes and state whether each absorbs or releases energy, and to interpret a heating or cooling curve, especially the flat plateaus where a phase change happens. The key idea is that during a phase change the temperature stays constant because energy is used to change the arrangement of particles rather than their speed.
The phase changes
The direction of energy flow follows the change in order. Going to a less ordered state (more particle freedom) requires energy input, so melting, vaporization and sublimation are endothermic (absorb energy). Going to a more ordered state releases energy, so freezing, condensation and deposition are exothermic (release energy).
Why temperature is constant during a phase change
So while ice melts at , all the added heat is used to pull the water molecules out of their fixed lattice; the temperature does not rise until every bit of ice has melted. The same holds at the boiling point. This is why a phase change appears as a horizontal line on a temperature-versus-time graph.
Reading a heating curve
A heating curve plots temperature against time (or heat added) as a substance is heated steadily from solid to gas. It has alternating sloped and flat regions:
- Sloped sections show a single phase being warmed: the particles gain kinetic energy and the temperature rises. The solid warms, then (after melting) the liquid warms, then (after boiling) the gas warms.
- Flat plateaus show phase changes at constant temperature: the first plateau is melting (at the melting point) and the second is boiling (at the boiling point). Both phases coexist along a plateau.
A cooling curve is the mirror image, sloping down with plateaus at the freezing and condensation points.
Try this
Q1. Name the phase change from liquid to gas. [1 point]
- Cue. Vaporization (boiling or evaporation).
Q2. State whether freezing absorbs or releases energy. [1 point]
- Cue. Releases energy; the particles slow and form a more ordered solid, so it is exothermic.
Exam-style practice questions
Practice questions written in the style of VDOE exam questions on this dot point, with worked answer explainers. The year tag is the paper they imitate, not the source.
SOL (multiple choice)1 marksDuring the melting of a pure solid, the temperature of the sample (A) increases (B) decreases (C) remains constant (D) increases then decreasesShow worked answer β
The answer is (C) remains constant.
During a phase change the added energy goes into breaking the attractions between particles, not into increasing their average kinetic energy, so the temperature stays constant until the change is complete. On a heating curve this shows as a flat plateau at the melting point. Once all the solid has melted, the temperature rises again.
The trap is assuming continuous heating always raises temperature; during a phase change the energy changes the state, not the temperature.
SOL (tech-enhanced, ordering)2 marks(a) Name the phase change from a gas directly to a solid. (b) State whether energy is absorbed or released during condensation.Show worked answer β
A 2-point item on phase-change names and energy.
(a) Phase change (1 point): deposition (gas to solid directly).
(b) Condensation (1 point): energy is released, because particles slow and come together as a gas becomes a liquid.
Markers reward the correct name and the correct energy direction. Changes toward a more ordered state (condensation, freezing, deposition) release energy; changes toward a less ordered state (melting, vaporization, sublimation) absorb energy.
Related dot points
- States of matter and kinetic molecular theory: describe solids, liquids and gases in terms of particle arrangement and motion, and state the assumptions of kinetic molecular theory.
A focused Virginia SOL Chemistry answer on the states of matter under CH.4: how particles are arranged and move in solids, liquids and gases, the link between temperature and average kinetic energy, and the assumptions of kinetic molecular theory.
- The gas laws: use Boyle's law, Charles's law, Gay-Lussac's law and the combined gas law to relate the pressure, volume and temperature of a gas.
A focused Virginia SOL Chemistry answer on the gas laws under CH.4: Boyle's law (pressure and volume), Charles's law (volume and temperature), Gay-Lussac's law (pressure and temperature), and the combined gas law, with worked calculations and the need for Kelvin temperature.
- The ideal gas law and molar volume: use the ideal gas law to relate pressure, volume, temperature and moles, and use the molar volume of a gas at STP.
A focused Virginia SOL Chemistry answer on the ideal gas law under CH.4: the equation PV = nRT and the value of R, when to use it instead of the combined gas law, and the molar volume of a gas (22.4 L per mole at STP).
- Endothermic and exothermic reactions: distinguish endothermic and exothermic processes by the direction of energy flow and the sign of the enthalpy change.
A focused Virginia SOL Chemistry answer on reaction energy under CH.6: the difference between endothermic and exothermic reactions, the direction of energy flow, the sign of the enthalpy change, and how temperature change signals each type.
- Solutions, solubility and concentration: describe solutes, solvents and the dissolving process, the factors that affect rate of dissolving and solubility, and how to read a solubility curve.
A focused Virginia SOL Chemistry answer on solutions under CH.5: solute and solvent, the dissolving process and like dissolves like, the factors that change the rate of dissolving and solubility, saturated and unsaturated solutions, and reading a solubility curve.
Sources & how we know this
- 2018 Science Standards of Learning - Chemistry β Virginia Department of Education (2018)
- Chemistry Curriculum Framework β Virginia Department of Education (2018)